The Nobel Prize in Chemistry 1981
Kenichi Fukui, Roald Hoffmann
I came to a
happy Jewish family in dark days in Europe. On July 18, 1937 I
was born to Clara (née Rosen) and Hillel Safran in Zloczow,
Poland. This town, typical of the Pale of the Settlement, was
part of Austria-Hungary when my parents were born. It was Poland
in my time and is part of the Soviet Union now. I was named after
Roald Amundsen, my first Scandinavian connection. My father was a
civil engineer, educated at the Lvov (Lemberg) Polytechnic, my
mother by training a school teacher.
In 1939 the war began. Our part of Poland was under Russian occupation from 1939-1941. Then in 1941 darkness descended, and the annihilation of Polish Jewry began. We went to a ghetto, then a labor camp. My father smuggled my mother and me out of the camp in early 1943, and for the remainder of the war we were hidden by a good Ukrainian in the attic of a school house in a nearby village. My father remained behind in the camp. He organized a breakout attempt which was discovered. Hillel Safran was killed by the Nazis and their helpers in June 1943. Most of the rest of my family suffered a similar fate. My mother and I, and a handful of relatives, survived. We were freed by the Red Army in June 1944. At the end of 1944 we moved to Przemysl and then to Krakow, where I finally went to school. My mother remarried, and Paul Hoffmann was a kind and gentle father to me until his death, two months prior to the Nobel Prize announcement.
In 1946 we left Poland for Czechoslovakia. From there we moved to a displaced persons' camp, Bindermichl, near Linz, in Austria. In 1947 we went on to another camp in Wasseralfingen bei Aalen in Germany, then to München. On Washington's Birthday 1949 we came to the United States.
I learned English, my sixth language at this point, quite quickly. After P.S. 93 and P.S. 16, Brooklyn, I went on to the great Stuyvesant High School, one of New York's selective science schools. Among my classmates were not only future scientists but lawyers, historians, writers - a remarkable group of boys. In the summers I went to Camp Juvenile in the Catskills, a formative experience. Elinor, my younger sister, was born in 1954.
In 1955 I began at Columbia College as a premedical student. That summer and the next I worked at the National Bureau of Standards in Washington with E.S. Newman and R.E. Ferguson. The summer after I worked at Brookhaven National Laboratory, with J.P. Cumming. These summers were important because they introduced me to the joys of research, and kept me going through some routine courses at Columbia. I did have some good chemistry teachers, G.K. Fracnkel and R.S. Halford, and a superb teaching assistant, R. Schneider. But I must say that the world that opened up before me in my non science courses is what I remember best from my Columbia days. I almost switched to art history.
In 1958 I began graduate work at Harvard. I intended to work with W.E. Moffitt, a remarkable young theoretician, but he died in my first year there. A young instructor, M.P. Gouterman, was one of the few faculty members at Harvard who at that time was interested in doing theoretical work, and I began research with him. In the summer of 1959 I got a scholarship from P.O. Lowdin's Quantum Chemistry Group at Uppsala to attend a Summer School. The school was held on Lidingö, an island outside of Stockholm. I met Eva Börjesson who had a summer job as a receptionist at the school, and we were married the following year.
I came back to Harvard, began some abortive (and explosive) experimental work, and Eva and I took off for a year to the Soviet Union. It was the second year of the U.S.-U.S.S.R graduate student exchange. I worked for 9 months at Moscow University with A.S. Davydov on excitor theory. Eva and I lived in one of the wings, Zona E, of that great central building of Moscow University. My proficiency in Russian and interest in Russian culture date from that time.
On returning to the U.S. I switched research advisors and started to work with W.N. Lipscomb, who had just come to Harvard. Computers were just coming into use. With Lipscomb's encouragement and ebullient guidance, L.L. Lohr and I programmed what was eventually called the extended Hückel method. I applied it to boron hydrides and polyhedral molecules in general. One day I discovered that one could get the barrier to internal rotation in ethane approximately right using this method. This was the beginning of my work on organic molecules.
In 1962 I received my doctorate, as the first Harvard Ph.D. of both Lipscomb and Gouterman. Several academic jobs were available, and I was also offered a Junior Fellowship in the Society of Fellows at Harvard. I chose the Junior Fellowship. The three ensuing years in the Society (1962 - 65), gave me the time to switch my interests from theory to applied theory, specifically to organic chemistry. It was EJ. Corey who taught me, by example, what was exciting in organic chemistry. I began to look at all kinds of organic transformations, and so I was prepared when in the Spring of 1964 R.B. Woodward asked me some questions about what subsequently came to be called electrocyclic reactions. That last year at Harvard was exciting. I was learning organic chemistry at a great pace, and I had gained access to a superior mind. R.B. Woodward possessed clarity of thought, powers of concentration, encyclopedic knowledge of chemistry, and an aesthetic sense unparalleled in modern chemistry. He taught me, and I have taught others.
The 1962 - 65 period was creative in other ways as well: Our two children, Hillel Jan and Ingrid Helena, were born to Eva and me.
In 1965 I came to Cornell where I have been ever since. A collegial department, a great university and a lovely community have kept me happy. I am now the John A. Newman Professor of Physical Science. I have received many of the honors of my profession. I am especially proud that in addition to the American Chemical Society's A.C. Cope Award in Organic Chemistry, which I received jointly with R.B. Woodward in 1973, I have just been selected for the Society's Award in Inorganic Chemistry in 1982, the only person to receive these two awards in different subfields of our science.
I have been asked to summarize my contributions to science.
My research interests are in the electronic structure of stable and unstable molecules, and of transition states in reactions. I apply a variety of computational methods, semiempirical and nonempirical, as well as qualitative arguments, to problems of structure and reactivity of both organic and inorganic molecules of medium size. My first major contribution was the development of the extended Huckel method, a molecular orbital scheme which allowed the calculation of the approximate sigma- and pie- electronic structure of molecules, and which gave reasonable predictions of molecular conformations and simple potential surfaces. These calculations were instrumental in a renaissance of interest in sigma electrons and their properties. My second major contribution was a two-pronged exploration of the electronic structure of transition states and intermediates in organic reactions. In a fruitful collaboration R.B. Woodward and I applied simple but powerful arguments of symmetry and bonding to the analysis of concerted reactions. These considerations have been of remarkable predictive value and have stimulated much productive experimental work. In the second approach I have analyzed, with the aid of various semiempirical methods, the molecular orbitals of most types of reactive intermediates in organic chemistry-carbonium ions, diradicals, methylenes, benzynes, etc.
Recently I and my collaborators have been exploring the structure and reactivity of inorganic and organometallic molecules. Approximate molecular orbital calculations and symmetry-based arguments have been applied by my research group to explore the basic structural features of every kind of inorganic molecule, from complexes of small diatomics to clusters containing several transition metal atoms. A particularly useful theoretical device, the conceptual construction of complex molecules from MLn fragments, has been used by my research group to analyze cluster bonding and the equilibrium geometries and conformational preferences of olefin and polyene metal carbonyl complexes. A satisfactory understanding of the mode of binding of essentially every ligand to a metal is now available, and a beginning has been made toward understand ing organometallic reactivity with the exploration of potential energy surfaces for ethylene insertion, reductive elimination and alkyl migrative insertion reactions. Several new structural types, such as the triple-decker and porphyrin sandwiches, have been predicted, and recently synthesized by others. On the more inorganic side, we have systematically explored the geometries, polytopal rearrangement and substitution site preferences of five, six, seven and eight coordination, the factors that influence whether certain ligands will bridge or not, the constraints of metal-metal bonding, and the geometry of uranyl and other actinide complexes. I and my coworkers are beginning work on extended solid state structures and the design of novel conducting systems.
The technical description above does not communicate what I think is my major contribution. I am a teacher, and I am proud of it. At Cornell University I have taught primarily undergraduates, and indeed almost every year since 1966 have taught first-year general chemistry. I have also taught chemistry courses to non-scientists and graduate courses in bonding theory and quantum mechanics. To the chemistry community at large, to my fellow scientists, I have tried to teach "applied theoretical chemistry": a special blend of computations stimulated by experiment and coupled to the construction of general models - frameworks for understanding.
From Les Prix Nobel. The Nobel Prizes 1981, Editor Wilhelm Odelberg, [Nobel Foundation], Stockholm, 1982
This autobiography/biography was written at the time of the award and later published in the book series Les Prix Nobel/Nobel Lectures. The information is sometimes updated with an addendum submitted by the Laureate.
Added in 1992
In the last decade I and my coworkers have
begun to look at the electronic structure of extended systems in
one-, two-, and three dimensions. Frontier orbital arguments find
an analogue in this work, in densities of states and their
partitioning. We have introduced an especially useful tool, the
COOP curve. This is the solid state analogue of an overlap
population, showing the way the bond strength depends on electron
count. My group has studied molecules as diverse as the
platinocyanides, Chevrel phases, transition metal carbides,
displacive transitions in NiAs, MnP and NiP, new metallic forms
of carbon, the making and breaking of bonds in the solid state
and many other systems. One focus of the solid state work has
been on surfaces, especially on the interaction of CH4
, acetylene and CO with specific metal faces. The group has been
able to carry through unique comparisons of inorganic and surface
reactions. And in a book "Solids and Surfaces. A Chemist's View
of Bonding in Extended Structures," I've tried to teach the
chemical community just how simple the concepts of solid state
physics are. And, a much harder task, to convince physicists that
there is value in chemical ways of thinking.
In 1986-88 I participated in the production of a television course in introductory chemistry. "The World of Chemistry" is a series of 26 half-hour episodes developed at the University of Maryland and produced by Richard Thomas. The project has been funded by Annenberg/the Corporation for Public Broadcasting. I am the Presenter for the series which began to be aired on PBS in 1990, and will also be seen in many other countries.
My first real introduction to poetry came at Columbia from Mark Van Doren, the great teacher and critic whose influence was at its height in the 1950's. Through the years I maintained an interest in literature, particularly German and Russian literature. I began to write poetry in the mid-seventies, but it was only in 1984 that a poem was first published. I own much to a poetry group at Cornell that includes A.R. Ammons, Phyllis Janowitz and David Burak, as well as to Maxine Kumin. My poems have appeared in many magazines and have been translated into French, Portuguese, Russian and Swedish. My first collection, "The Metamict State", was published by the University of Central Florida Press in 1987, and is now in a second printing. A second collection, "Gaps and Verges", was also published by the University of Central Florida Press, in 1990. Articles on my poetry have appeared in Literaturnaya Gazeta and Studies in American Jewish Literature. I received the 1988 Pergamon Press Fellowship in Literature at the Djerassi Foundation, Woodside, California, where I was in residence for three years.
It seems obvious to me to use words as best as I can in teaching myself and my coworkers. Some call that research. Or to instruct others in what I've learned myself, in ever-widening circles of audience. Some call that teaching. The words are important in science, as much as we might deny it, as much as we might claim that they just represent some underlying material reality.
It seems equally obvious to me that I should marshal words to try to write poetry. I write poetry to penetrate the world around me, and to comprehend my reactions to it.
Some of the poems are about science, some not. I don't stress the science poems over the others because science is only one part of my life. Yet there are several reasons to welcome more poetry that deals with science.
Around the time of the Industrial Revolution - perhaps in reaction to it, perhaps for other reasons - science and its language left poetry. Nature and the personal became the main playground of the poet. That's too bad for both scientists and poets, but it leaves lots of open ground for those of us who can move between the two. If one can write poetry about being a lumberjack, why not about being a scientist? It's experience, a way of life. It's exciting.
The language of science is a language under stress. Words are being made to describe things that seem indescribable in words - equations, chemical structures and so forth. Words do not, cannot mean all that they stand for, yet they are all we have to describe experience. By being a natural language under tension, the language of science is inherently poetic. There is metaphor aplenty in science. Emotions emerge shaped as states of matter and more interestingly, matter acts out what goes on in the soul.
One thing is certainly not true: that scientists have some greater insight into the workings of nature than poets. Interestingly, I find that many humanists deep down feel that scientists have such inner knowledge that is barred to them. Perhaps we scientists do, but in such carefully circumscribed pieces of the universe! Poetry soars, all around the tangible, in deep dark, through a world we reveal and make.
It should be said that building a career in poetry is much harder than in science. In the best chemical journal in the world the acceptance rate for full articles is 65%, for communications 35%. In a routine literary journal, far from the best, the acceptance rate for poems is below 5%.
Writing, "the message that abandons", has become increasingly important to me. I expect to publish four books for a general or literary audience in the next few years. Science will figure in these, but only as a part, a vital part, of the risky enterprise of being human.
Copyright © The Nobel Foundation 1981
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