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1901 2011
Prize category:
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The Nobel Prize in Chemistry 1903
Svante Arrhenius
Biography
Svante August Arrhenius was born on February
19, 1859, the son of Svante Gustaf Arrhenius and Carolina
Christina Thunberg. His ancestors were farmers; his uncle became
Professor of Botany and Rector of the Agricultural High School at Ultuna near Uppsala and
later Secretary of The Swedish Academy of Agriculture. His father
was a land surveyor employed by the University of
Uppsala and in charge of its estates at Vik, where Svante was
born. The family moved to Uppsala in 1860. The boy was educated
at the Cathedral school where the rector was a good physics
teacher. From an early age Svante had shown an aptitude for
arithmetical calculations, and at school he was greatly
interested in mathematics and physics. In 1876 he entered the
University of Uppsala, studying mathematics, chemistry and
physics. The practical instruction in physics was not of the
best, and in 1881 he went to Stockholm to work under Professor E.
Edlund at the Academy of Sciences.
Here, Arrhenius began by assisting Edlund in his work on
electromotive force measurements in spark discharges but soon
moved to an interest of his own. This resulted in his thesis
(1884) Recherches sur la conductibilité galvanique des
électrolytes (Investigations on the galvanic
conductivity of electrolytes). From his results the author
concluded that electrolytes, when dissolved in water, become to
varying degrees split or dissociated into electrically opposite
positive and negative ions. The degree to which this dissociation
occurred depended above all on the nature of the substance and
its concentration in the solution - being more developed the
greater the dilution. The ions were supposed to be the carriers
of the electric current, e.g. in electrolysis, but also of the
chemical activity. The relation between the actual number of ions
and their number at great dilution (when all the molecules were
dissociated) gave a quantity of special interest ("activity
constant").
The idea of a connection between electricity and chemical
affinity, once advocated by Berzelius, had, however, so
completely vanished from the general consciousness of scientists
that the value of Arrhenius' publication was not well understood
by the science faculty at Uppsala, where the dissertation took
place. On the other hand, Otto Pettersson, Professor of Chemistry
at Stockholms
Högskola, emphasized the originality of the
dissertation*, and Wi. Ostwald travelled to Uppsala to make
the acquaintance of the young author. The fundamental importance
of Arrhenius' work was thus made clear, and at the end of 1884 he
got a docentship at Uppsala in physical chemistry - the first in
Sweden in this new branch of science. Through Edlund's influence
he was awarded a travelling fellowship from the Academy of
Sciences which enabled him to work in 1886 with Ostwald in Riga
and with Kohlrausch in Würzburg. In 1887 he was with
Boltzmann in Graz and in 1888 he worked with van 't Hoff in Amsterdam. During these
years Arrhenius was able to prove the influence of the
electrolytic dissociation on the osmotic pressure, the lowering
of the freezing point and increase of the boiling point of
solutions containing electrolytes. Later on he studied its
importance in connection with biological problems such as the
relationship between toxins and antitoxins, serum therapy, its
role for digestion and absorption as well as for the gastric and
pancreatic juices. The paramount importance of the electrolytic
dissociation theory is today universally acknowledged, even if
certain modifications have been found necessary.
In 1891, Arrhenius declined a professorship offered to him from
Giessen, Germany, and soon afterwards he obtained a lectureship
in physics at Stockholms Högskola. In 1895 he became
Professor of Physics there. He was in addition Rector from 1897
to 1905, when he retired from the professorship. He had got an
invitation to a professorship in Berlin, and the Academy of
Sciences then decided (1905) to start a Nobel Institute for
Physical Chemistry with Arrhenius as its chief. Initially he had
to work in a rented flat, but a new building was inaugurated in
1909. A large number of collaborators came to him from Sweden and
from other countries, and helped to give his ideas wider
currency.
In 1900 Arrhenius published his Lärobok i teoretisk
elektrokemi (Textbook of theoretical electrochemistry), in
1906 followed Theorien der Chemie (Theories of Chemistry)
and Immunochemistry and in 1918 the Silliman lectures
Theories of solutions. He took a lively interest in
various branches of physics, as illustrated by his theory of the
importance of the CO2-content of the atmosphere for
the climate, his discussion of the possibility that radiation
pressure might enable the spreading of living spores through the
universe (panspermy) and by his various contributions to our
knowledge of the northern lights. In 1903 appeared his
Lehrbuch der kosmischen Physik (Textbook of cosmic
physics).
Many lectures and short publications gave witness of his interest
and capacity for writing for the general public. Especially
during the last decades of his life he published a number of
popular books, which were usually translated into several
languages and appeared in numerous editions. To these belong
Världarnas utveckling (1906, Worlds in the Making),
Stjärnornas Öden (1915, Destiny of the Stars)
and others. In 1913 appeared Smittkopporna och deras
bekämpande (Smallpox and its combating) and in 1919
Kemien och det moderna livet (Chemistry and modern
Life).
Arrhenius was elected a Foreign member of the Royal Society in
1911, and was awarded the Society's Davy medal and also the
Faraday Medal of the Chemical Society (1914). Among the many
tokens of distinction that he received were honorary degrees from
the Universities of Birmingham, Cambridge, Edinburgh,
Greifswald, Groningen, Heidelberg, Leipzig and Oxford.
Arrhenius was a contented man, happy in his work and in his
family life. During the First World War, he made successful
efforts to release and repatriate German and Austrian scientists
who had been made prisoners of war.
He was twice married - in 1894 to Sofia Rudbeck, by whom he had
one son, and in 1905 to Maria Johansson by whom he had one son
and two daughters.
He died at Stockholm on October 2, 1927, and is buried at
Uppsala.
* The Stockholms Högskola (High School of Stockholm) corresponded in those days to a science faculty of the universities, but it was a private foundation and did not have the right to hold examinations for degrees or to judge the value of theses. It was not until 1960 that the University of Stockholm, with its many faculties, was established by the State.
From Nobel Lectures, Chemistry 1901-1921, Elsevier Publishing Company, Amsterdam, 1966
This autobiography/biography was written at the time of the award and first published in the book series Les Prix Nobel. It was later edited and republished in Nobel Lectures. To cite this document, always state the source as shown above.
Copyright © The Nobel Foundation 1903
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