Presentation Speech by Professor H. Pleijel, Chairman of the Nobel Committee for Physics of the Royal Swedish Academy of Sciences, on December 10, 1938
Your Majesty, Your Royal Highnesses, Ladies
With what we know today of the structure of atoms, we understand perfectly the hopeless task undertaken by alchemists of old, striving to transmute the different elements one to another, and to transform lead and mercury into gold. With the means at their command, they could not work on the essential part of the atom, that is to say the nucleus. The chemical binding forces and most of the physical phenomena, such as radiation, etc., originate in the outermost parts of the atom, in the light, negatively charged electrons orbiting around the nucleus. The characteristic feature of atoms and what makes atoms different from each other, however, is the number of positive unit charges of electricity, or the number of protons, contained in the nucleus. It is this charge which holds together the light, negative electrons that spread, like the planets round the sun, in circular layers round the central nucleus.
At the present level of our knowledge, everything points to the fact that the nuclei of the atoms are composed of particles of two types, one being a heavy particle that has been given the name of neutron as it lacks electric charge, and the other being called proton, of the same mass as the neutron but with a positive unit charge. A proton is nothing but the nucleus of the lightest atom, i.e. hydrogen. A helium nucleus has two protons and two neutrons; the atom of carbon has six protons and six neutrons, and so on. The atoms are numbered according to the number of protons, or unit charges in the nucleus, with hydrogen as number 1 and uranium as number 92, which is the heaviest element known to date.
Meanwhile, it has been found that the nucleus of an atom can contain a number of neutrons less than or in excess of the normal. These atoms, that present the same physical and chemical qualities as the normal atom except that the weight is different, have received the name of isotopes. As an example of an isotope, we can cite the heavy-hydrogen atom discovered by Urey which is a constituent of so-called heavy water. There exist hydrogen isotopes with one or two neutrons in the nucleus.
After all the fruitless attempts at the transmutation of one element into another, the firm conviction grew last century that the different atoms, 92 in number, were indestructible and immutable units of the structure of matter. There was thus great sensation when the Frenchman Becquerel, in 1892, discovered that the element uranium distintegrated giving off strong radiation. Research on this radiation proved that it consisted among others of the helium nuclei that were emitted at very high speed from the uranium atoms. Thus, when one part of the uranium nuclei disintegrates explosively, new substances are formed that disintegrate in their turn, giving off radiations, and so on, until a final stable product is formed which is found to be lead. Among the substances included in this chain, there is the highly radioactive substance radium, which Madame Curie discovered and succeeded in producing. Soon after the radioactivity of uranium was discovered, it was established that this same characteristic occurred in another element, thorium, and later it appeared that this was also the case with the element called actinium. The end-product of the disintegration of these two last-named elements is lead also. However, the lead obtained in these three series is not identical, in so far as the number of constituent neutrons is concerned. The lead that comes from the uranium has 124 neutrons in the nucleus, that which comes from thorium has 126 and that which comes from actinium has 125. So we have three isotopes of lead. Lead as found in nature is usually a mixture of these three types.
It must be noted in this respect that however strong the effect of a substance that is radioactive, it is in many instances only a very small part of the number of atoms that disintegrates. Thus, for a half of the number of uranium atoms to disintegrate, it would take four and a half thousand million years. For radium, the corresponding length of time would be one thousand six hundred years. Other radioactive materials would by contrast only take seconds or days for half of the number of atoms to disintegrate.
As the idea of immutability of the atoms of the elements had to be abandoned, one was back at the age-old problem of the alchemists, the transmutation of the elements. Lord Rutherford was the first to put forward the idea that it would be possible, with the help of the heavy-helium nuclei that are thrown off at great speed by the natural radioactive substances, to split atoms. He met with success in several cases. For the sake of example, we will be content to mention that if a nitrogen nucleus has been struck by the bombarding helium nuclei, a hydrogen nucleus is ejected from the former, and that the rests together with the captured helium nucleus form an oxygen nucleus. By this means helium and nitrogen were thus changed into oxygen and hydrogen. The atom of oxygen that was obtained by this method was however not the ordinary oxygen atom, an atom that has eight neutrons in the nucleus, but an oxygen atom with nine neutrons. This meant that an oxygen isotope had been obtained. This occurs in nature, although rarely; among 12,500 ordinary oxygen atoms, one oxygen isotope is found.
Rutherford's experiments on the splitting of atoms have later been continued by the husband-and-wife team Joliot-Curie, among others, who also used helium nuclei as projectiles. They found that often when new isotopes were formed, these isotopes were radioactive, and distintegrated emitting radioactive radiations. This discovery was of great importance, for it opened up the possibility of obtaining, by artificial processes, substances capable of replacing radium, a material that was both very costly and hard to come by.
Using helium nuclei and also hydrogen nuclei as projectiles, however, one can not split atoms with atomic numbers higher than 20; therefore, only part of the lighter elements of the series of atoms can so be split.
It was granted to today's Nobel Prize winner, Professor Fermi, to succeed in shattering even the heavier and the heaviest elements in the Periodic System.
Fermi used neutrons as projectiles in his experiments.
We have earlier spoken of the neutron as one of the two building-stones in atom nuclei. The existence of the neutron is however only a recent discovery. Rutherford had suspected the existence of a heavy particle without electric charge and had even given it the name neutron; it was given to one of his pupils, Chadwick, to find the neutron in the extremely strong radiation given off by beryllium subjected to the effect of a radioactive substance. The neutron has qualities that make it particularly suitable as a projectile in atomic fission. Both the helium nucleus and the hydrogen nucleus carry electric charges. The strong electric forces of repulsion developed when such a charged particle comes within reach of an atomic nucleus, deflect the projectile. The neutron being uncharged continues on its course without suffering any hindrance until it is stopped by direct impact on a nucleus. As the dimensions of the nuclei are extremely small compared with the distances that separates the different parts of the atoms, such impacts are of rare occurrence. As a result, beams of neutrons, experiment has shown, can pass through armour-plates metres thick without appreciable reduction in speed taking place.
The result which Fermi was able to achieve by using neutron bombardments have proved to be of inestimable value, and have shed new light on the structure of atom nuclei.
At first, the source of radiation was a mixture of beryllium powder and a radioactive substance. Today, neutrons are artificially produced by bombarding beryllium or lithium with heavy-hydrogen nuclei, whereby these substances emit neutrons with high energy. The neutron beams so produced are particularly powerful.
When using neutrons as projectiles, these are captured in the nucleus. In the case of the lighter elements, a hydrogen nucleus or a helium nucleus is ejected instead. With the heavier elements, however, the forces that interlink the atomic parts are so strong that, at least with neutron speeds that can be obtained by present methods, there is no ejection of any material part. The surplus energy disappears in the form of electromagnetic radiations (gamma-radiations). As there is no variation in the charge, an isotope is obtained of the initial substance. This isotope, in many cases unstable, disintegrates giving off radioactive radiations. Radioactive materials are thus obtained as a rule.
It was some six months after their first experiment with neutron irradiation that Fermi and his co-workers came by chance on a new discovery which proved to be of the greatest importance. They observed namely that the effect of neutron irradiation was often extremely increased, when the rays were allowed to pass through water or paraffin. Minute study of this phenomenon showed that the speed of the neutrons was slowed down on impact with the hydrogen nuclei which were present in these substances. Contrary to what one had reasons to believe, it appeared that the slow neutrons had a much more powerful effect than the fast neutrons. It was further found that the strongest effect was achieved at a certain speed, which is different for different substances. This phenomenon has therefore been compared with resonance found in optics and acoustics.
With low-speed neutrons, Fermi and his co-workers were successful in producing radioactive isotopes of all the elements with the exception of hydrogen and helium and part of the radioactive substances. More than four hundred new radioactive substances have thus been obtained. A certain number of these has effects stronger than radium as regards radioactivity. Of these substances, more than half were products of bombardment by neutrons. The half-lives of these artificial radioactive substances appear comparatively short, varying from one second to several days.
As we have said, during the irradiation of heavy elements by neutrons, the neutrons are captured and incorporated in the nucleus, and an isotope is thus formed of the primary substance, and this isotope is radioactive. When the isotope decays, however, negative electrons - as can be proved - are projected and new substances are formed with higher positive charges, and therefore substances with higher rank number.
This general pattern that Fermi has found to be the rule when heavy substances are subjected to irradiation by neutrons, took on special interest when applied by him to the last element in the series of elements, viz. uranium, which has rank number 92. Following this process, the first product of disintegration should be an element with 93 positive electric charges and a new element would thus have been found, lying outside the old series. Fermi's researches on uranium made it most probable that a series of new elements could be found, which exist beyond the element up to now held to be the heaviest, namely uranium with rank number 92. Fermi even succeeded in producing two new elements, 93 and 94 in rank number. These new elements he called Ausenium and Hesperium.
Along with Fermi's significant discoveries, and to a certain extent equivalent, can be placed his experimental skill, his brilliant inventiveness and his intuition. These qualities have found expression in the creation of refined research methods which made it possible to demonstrate the existence of these newly formed substances, which occur in extremely small quantities. The same goes for the measurement of the speed at which the different radioactive products disintegrate, particularly since in many cases several disintegration products with different half-lives are simultaneously involved.
Professor Fermi. The Royal Swedish Academy
of Sciences has awarded you the Nobel Prize for Physics for 1938
for your discovery of new radioactive substances belonging to the
entire field of the elements and for the discovery, which you
made in the course of your studies, of the selective powers of
the slow neutrons.
We offer our congratulations and we express the most vivid admiration for your brilliant researches, which throw new light on the structure of atomic nuclei and which open up new horizons for the future development of atomic investigation.
We ask you now to receive the Nobel Prize from the hands of His Majesty the King.
From Nobel Lectures, Physics 1922-1941, Elsevier Publishing Company, Amsterdam, 1965
Copyright © The Nobel Foundation 1938